無機ナノ材料研究室 (八木・由井・齊藤研究室)

新潟大学大学院自然科学研究科・新潟大学工学部機能材料工学科

最近の主要論文

2013年>

 

1) Synthesis, characterization and heterogeneous catalysis for water oxidation of a di-manganese complex with 4’-(4-pyridyl)-2,2’:6’,2’’-terpyridine)

H. Yamazaki, T. Ueno, K. Aiso, M. Hirahara, T. Aoki, T. Nagata, S. Igarashi, M. Yagi, Polyhedron, 2013, 52, 455-460.

 

2) Arrangement effect of di-μ-oxo dimanganese catalyst and Ru(bpy)32+ photoexcitation centers adsorbed in mica on visible-light-derived water oxidation

M. Hirahara, H. Yamazaki, S. Yamada, K. Matsubara, K. Saito, T. Yui, M. Yagi, Catal. Sci. Technol., 2013, in press.

 

3) Mechanisms of Photoisomerization and Water-Oxidation Catalysis of Mononuclear Ruthenium(II) Monoaquo Complexes

M. Hirahara, M. Z. Ertem, M. Komi, H. Yamazaki, C. J. Cramer, M. Yagi, Inorg. Chem. 2013, 52(11), 6354-6364.

 

4) Fabrication of highly crystalline SnNb2O6 shell with a visible light response on NaNbO3 nanowire core

K. Saito, A. Kudo, Inorg. Chem. 2013, 52(10), 5621-5623.

 

5) Diameter-dependent photocatalytic performance of niobium pentoxide nanowire.

      K. Saito, A. Kudo, Dalton Trans. 2013, 42, 6867-6872.

 

6) 「二酸化炭素利用の人工光合成システムの開発」

     松原一喜, 由井樹人, 二酸化炭素の直接利用最新技術, NTS, 2013, 91-102.

 

7)CO2の還元・光資源化に向けた光触媒技術;分子および半導体光触媒」

     由井樹人,松原一喜, 人工光合成 実用化に向けた最新技術 〜水素利用・有機物合成・エネルギー・CO2還元〜, 情報機構, 2013, 113-122.

                                      

2012年>

 

8) Adsorptive and kinetic properties on photocatalytic hydrogenation of aromatic ketones upon UV irradiated polycrystalline titanium dioxide: differences between acetophenone and its trifluoromethylated derivative

       S. Kotani, E. Yoshioka, K. Saito, A. Kudo, H. Miyabe, J. Phys. Chem. C. 2012, 116(33), 17705-17713.

 

9) Substituent effects on core structures and heterogeneous catalytic activities of MnIII(μ-O)2MnIV dimers with 2,2’:6’,2’’-terpyridine derivative ligands for water oxidation

H. Yamazaki, S. Igarashi, T. Nagata, M. Yagi, Inorg. Chem. 2012, 51(3), 1530–1539.

 

10) 「酸化物半導体複合体の光機能」

     由井樹人, 高木克彦, 革新機能材料の開発と応用展開, シーエムシー出版, 2012, 192-194.

 

11) 「無機ナノシート積層空間を利用した光エネルギーの化学エネルギーへの変換」

     由井樹人, 高木克彦, 革新機能材料の開発と応用展開, シーエムシー出版, 2012, 37-43.

 

12) 「金属錯体による水の酸化触媒系の構築」

     平原将也, 八木政行, 月刊「化学工業」20129月号, 株式会社化学工業社, 2012, 8-11.

 

2011年>

 

13) Catalytic water oxidation to produce molecular oxygen by ruthenium complexes (Chapter 15), Ruthenium: Properties, Production and Applications (Edited by David B. Watson)

 H. Yamazaki, T. Miyagawa, A. Shouji, M. Kajita, M. Yagi, Nova Science Publishers, Inc., 2011, 399-411. (ISBN: 978-1-61761-550-4)

 

14) Stoichiometric photoisomerization of mononuclear ruthenium (II) monoaquo complexes controlling redox properties and water oxidation catalysis

H. Yamazaki, T. Hakamata, M. Komi, M. Yagi, J. Am. Chem. Soc., 2011, 133, 8846-8849.

 

15) New Development of molecular catalysts for water oxidation

M. Yagi, Bull. Jpn. Soc. Coord. Chem., 2011, 57, 67-74.

 

16) Highly active and tunable catalysts for O2 evolution from water based on mononuclear ruthenium (II) monoaquo complexes

M. Yagi, S. Tajima, M. Komi, H. Yamazaki, Dalton Trans., 2011, 40 (15), 3802-3804.

 

2010年>

 

17) Element-saving preparation of an efficient electrode catalyst based on self-assembly of Pt colloid nanoparticles onto an ITO electrode

M. Kajita, T. Kuwabara, D. Hasegawa, M. Yagi, Green Chem., 2010, 12, 2150-2152.

 

18) An artificial model of photosynthetic photosystem II: visible-light-derived O2 production from water by a di-μ-oxo-bridged manganese dimer as an oxygen evolving center

M. Yagi, M. Toda, S. Yamada, H. Yamazaki, Chem. Commun., 2010, 46, 8594-8596.

 

19) Electrocatalytic and photocatalytic water oxidation to dioxygen based on metal complexes

H. Yamazaki, A. Shouji, M. Kajita, M. Yagi, Coord. Chem. Rev., 2010, 254(21-22), 2483-2491.

 

2009年>

 

20) Synthetic models of photosynthetic water oxidizing complex (OEC): O2 evolution from water by heterogeneous manganese-oxo complexes, in Photosynthesis: Theory and Applications in Energy, Biotechnology and Nanotechnology (Edited by T. B. Buchner and N. H. Ewingen)

M. Yagi, H. Yamazaki, T. Aoki, K. Narita, Nova Science Publishers, Inc., New York, 2009. (ISBN: 978-1-60692-719-9).

 

21) Molecular catalysts for water oxidation toward artificial photosynthesis

M. Yagi, A. Syouji, S. Yamada, M. Komi, H. Yamazaki, S. Tajima, Photochem. Photobiol. Sci. (Special Issue: "Photosynthesis from Molecular Perspectives: Towards Future Energy Production), 2009, 8(2), 139-147.

 

22) Non-catalytic O2 evolution by [(OH2)(Clterpy)Mn(µ-O)2Mn(Clterpy)(OH2)]3+ (Clterpy =4’-Chloro-2,2’:6’,2’’-terpyridine) adsorbed on mica in CeIV oxidation

H. Yamazaki, T. Nagata, M. Yagi, Photochem. Photobiol. Sci., 2009, 8(2), 204-209.

 

23) Chemical adsorption onto an ITO substrate of single-wall carbon nanotube functionalized by carboxylic groups as an efficient support for electrocatalyst

K. Sone, M. Yagi, Electranalysis, 2009, 21(2), 111-214.

 

2008年>

 

24) Influencing factors on electrochromic hysteresis performance of Ruthenium purple produced by a WO3 / tris(2,2’-bipyridine)ruthenium(II) / polymer hybrid film

K. Sone, M. Yagi, Electrochim. Acta., 2008, 53(22) 6535-6541.

 

25) Electrochemical synthesis, charge transport and multi-electron transfer control for a new semiconductor nanocomposite film with a functional molecule, in Electroanalytical Chemistry Research Trends (Edited by K. Hayashi)

K. Sone, M. Yagi, Nova Science Publishers, Inc., New York, 2008, 83-105. (ISBN: 978-1-60456-278-1)

 

26) Characterization and analysis of self-assembly of highly active colloidal catalyst for water oxidation onto transparent conducting oxide substrates

T. Kuwabara, E. Tomita, S. Sakita, D. Hasegawa, K. Sone, M. Yagi, J. Phys. Chem. C, 2008, 112(10), 3774-3779.

 

27) Preparation and photoelectrocatalytic activity of a nano-structured WO3 platelet film

M. Yagi, S. Maruyama, K. Sone, K. Nagai, T. Norimatsu, J. Solid State Chem., 2008, 181(1), 175-182.

 

28)電気化学的手法を用いた新機能分子複合膜の合成と電子移動解析」

    曽根浩司八木政行, Electrochemistry, 電気化学会, 2007, 75(11), 890-895.

 

2007年>

 

29) Efficient charge transport through a metal oxide semiconductor in the nanocomposite film with tris(2,2’-bipyridine)ruthenium(II)

K. Sone, M. Teraguchi, T. Kaneko, T. Aoki, M. Yagi, J. Phys. Chem. C, 2007, 111(31), 11636-11641.

 

30) Electrochemical and photosensitized redox reactions of a Prussian blue film layered on a WO3 / [Ru(bpy)3]2+ / polymer hybrid film

K. Sone, M. Teraguchi, T. Kaneko, T. Aoki, M. Yagi, ChemPhysChem, 2007, 8(9), 1357-1362.

 

31) Artificial model of photosynthetic oxygen evolving complex: catalytic O2 production from water by di-μ-oxo manganese dimers supported by clay compounds

M. Yagi, K. Narita, S. Maruyama, K. Sone, T. Kuwabara, K. Shimizu, Biochim. Biophys. Acta – Bioenergetics, 2007, 1767(6), 660-665.

 

2006年>

 

32) Characterization and activity analysis of catalytic water oxidation induced by hybridization of [(OH2)(terpy)Mn(µ-O)2Mn(terpy)(OH2)]3+ and clay compounds

K. Narita, T. Kuwabara, K. Sone, K. Shimizu, M. Yagi, J. Phys. Chem. B, 2006, 110(46), 23107-23114.

 

33) Electrochromic hysteresis of Prussian blue film arising from electron-transfer control by a tris(2,2’-bipyridine)ruthenium(II)-doped WO3 film as studied by a spectrocyclic voltammetry technique

K. Sone, K. Konishi, M. Yagi, Chem. Eur. J., 2006, 12(33), 8558-8565.

 

34) Insights into adsorption of uncharged macrocyclic complexes into a Nafion film: adsorption characteristics and analysis of tetraphenylporphyrine zinc(II)

T. Kuwabara, M. Yagi, J. Phys. Chem. B, 2006, 110(30), 14673-14677.

 

35) 「光合成酸素発生錯体モデル:不均一系マンガン錯体による水からの酸素発生」

        八木政行, 光合成研究, 2006, 16(47), 2-6

 

36) 「エネルギー変換デバイスのための高活性電極触媒」

        八木政行, OHM, オーム社, 2006, 93(6), 2-3.

 

37) Charge transport and catalysis by molecules confined in polymeric materials and application to future nano-devices for energy conversion

M. Yagi, M. Kaneko, Adv. Polym. Sci. 2006, 199, 143-188.

 

38) Spectrocyclic voltammetry of ruthenium purple electrodeposited on a WO3/tris(2,2’-bipyridine)ruthenium(II)/polymer hybrid film

K. Sone, M. Yagi, Macromol. Symp., 2006, 235(1), 179-186.

 

2005年>

 

39) Catalytic O2 evolution from water induced by adsorption of metal complexes onto heterogeneous matrixes

M. Yagi, Bull. Jpn. Soc. Coord. Chem. 2005(46), 15-21.

 

40) Self-assembly of active IrO2 colloid catalyst on an ITO electrode for efficient electrocatalytic water oxidation

M. Yagi, E. Tomita, S. Sakita, T. Kuwabara, K. Nagai, J. Phys. Chem. B, 2005, 109(46), 21489-21491.

 

41) Analysis and regulation of unusual adsorption of phthalocyanine Zinc (II) into a Nafion film as investigated by UV-Vis spectroscopic techniques

T. Kuwabara, M. Teraguchi, T. Kaneko, T. Aoki, M. Yagi, J. Phys. Chem. B, 2005, 109(44), 21202-21208.

 

42) Remarkably high activity of electrodeposited IrO2 film for electrocatalytic water oxidation

M. Yagi, E. Tomita, T. Kuwabara, J. Electroanal. Chem., 2005, 579(1), 83-88.

 

43) Preparation and multicolor electrochromic performance of a WO3 / tris(2,2’-bipyridine)ruthenium(II) / polymer hybrid film

M. Yagi, K. Sone, M. Yamada, S. Umemiya, Chem. Eur. J., 2005, 11(2), 767-775.