無機ナノ材料研究室 (八木・由井・齊藤研究室)

新潟大学大学院自然科学研究科・新潟大学工学部機能材料工学科

研究内容@ マンガン錯体を用いた光合成PSIIモデルの構築

<関連論文>

1) M. Yagi, M. Toda, S. Yamada, H. Yamazaki, An artificial model of photosynthetic photosystem II: visible-light-derived O2 production from water by a di-μ-oxo-bridged manganese dimer as an oxygen evolving center, Chem. Commun., 2010, 46, 8594-8596.

 

2) M. Yagi, H. Yamazaki, T. Aoki, K. Narita, Synthetic models of photosynthetic water oxidizing complex (OEC): O2 evolution from water by heterogeneous manganese-oxo complexes, in Photosynthesis: Theory and Applications in Energy, Biotechnology and Nanotechnology (Edited by T. B. Buchner and N. H. Ewingen), Nova Science Publishers, Inc., New York, 2009. (ISBN: 978-1-60692-719-9).

 

3) H. Yamazaki, T. Nagata, M. Yagi, Non-catalytic O2 evolution by [(OH2)(Clterpy)Mn(µ-O)2Mn(Clterpy)(OH2)]3+ (Clterpy = 4’-Chloro-2,2’:6’,2’’-terpyridine) adsorbed on mica in CeIV oxidation, Photochem. Photobiol. Sci., 2009, 8(2), 204-209.

 

4) M. Yagi, K. Narita, S. Maruyama, K. Sone, T. Kuwabara, K. Shimizu, Artificial model of photosynthetic oxygen evolving complex: catalytic O2 production from water by di-μ-oxo manganese dimers supported by clay compounds, Biochim. Biophys. Acta – Bioenergetics, 2007, 1767(6), 660-665.

 

5) K. Narita, T. Kuwabara, K. Sone, K. Shimizu, M. Yagi, Characterization and activity analysis of catalytic water oxidation induced by hybridization of [(OH2)(terpy)Mn(µ-O)2Mn(terpy)(OH2)]3+ and clay compounds, J. Phys. Chem. B, 2006, 110(46),23107-23114.

 

6) M. Yagi, K. Narita, Catalytic O2 evolution from water induced by adsorption of [(OH2)(terpy)Mn(μ-O)2Mn(terpy)(OH2)]3+ complex onto clay compounds, J. Am. Chem. Soc., 2004, 126(26), 8084-8085.

角丸四角形: 研究B

研究A

角丸四角形: 研究@

研究C

研究D

研究E

研究F

研究G

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